Synthesis, characterization and swelling performance of a temperature/pH-sensitive kappa-carrageenan graft copolymer

Abstract

A binary graft copolymerization of dimethylaminoethyl methacrylate (DMAEMA) and acrylic acid (AA) onto kappa-carrageenan (CG) was performed by using microwave irradiation in the presence of 4A'-Azobis(4-cyanovaleric acid) (ACVA). The structure of the CG-g-P(DMAEMA/AA) copolymers was confirmed using C-13 NMR, MR, DSCTFGA and XRD. The effects of the DMAEMA/AA ratio, the microwave power and irradiation duration, and the concentrations of CG and ACVA on grafting yield and grafting efficiency were all investigated, and the best values of them were found to be 150% and 85%, respectively. The lower critical solution temperatures (LCST) for CG-g-P(DMAEMA/AA) copolymers at various pH conditions were determined, and when the pH value of the medium was increased from 12 to 10, the LCST of the copolymer decreased from 53 degrees C to 39 degrees C. Moreover, swelling performance of the copolymers under various pH conditions was examined, and it was observed that the swelling ratio of the copolymer increased with a decrease in the pH value of the medium. (C) 2020 Elsevier B.V. All rights reserved.