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dc.contributor.authorÖzer, Demet
dc.contributor.authorKöse, Dursun Ali
dc.contributor.authorŞahin, Ozan
dc.contributor.authorAltuntaş Öztaş, Nurşen
dc.date.accessioned2019-05-10T09:38:59Z
dc.date.available2019-05-10T09:38:59Z
dc.date.issued2018
dc.identifier.citationOzer, D., Köse, D. A., Sahin, O., & Oztas, N. A. (2018). Study of structural, surface and hydrogen storage properties of boric acid mediated metal (sodium)-organic frameworks. Journal of Molecular Structure, 1157, 159-164.en_US
dc.identifier.issn0022-2860
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2017.12.063
dc.identifier.urihttps://hdl.handle.net/11491/575
dc.description.abstractThree boric acid mediated metal organic frameworks were synthesized by solution method with using succinic acid, fumaric acid and acetylene dicarboxylic acid as a ligand source and sodium as a metal source. The complexes were characterized by FT-IR, powder XRD, elemental analyses and single crystal measurements. The complexes with the formula, C4H18B2Na2O14, C4H16B2Na2O14 and C4H14B2Na2O14 were successfully obtained. BET surface area of complexes were calculated and found as 13.474 m2/g for catena-(tetrakis(?2-hydroxo)-(?2-trihydrogen borate)-(?2-succinato)-di-sodium boric acid solvate), 1.692 m2/g for catena-(tetrakis(?2-hydroxo)-(?2-trihydrogen borate)-(?2-fumarato)-di-sodium boric acid solvate) and 5.600 m2/g for catena-(tetrakis(?2-hydroxo)-(?2-trihydrogen borate)-(?2-acetylenedicarboxylato)-di-sodium boric acid solvate). Hydrogen storage capacities of the complexes were also studied at 77 K 1 bar pressure and found as 0.108%, 0.033%, 0.021% by mass. When different ligands were used, the pore volume, pore width and surface area of the obtained complexes were changed. As a consequence, hydrogen storage capacities also changed. © 2017 Elsevier B.V.en_US
dc.language.isoeng
dc.publisherElsevier B.V.en_US
dc.relation.isversionof10.1016/j.molstruc.2017.12.063en_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAcetylene Dicarboxylic Aciden_US
dc.subjectFumaric Aciden_US
dc.subjectHydrogen Storageen_US
dc.subjectSodiumen_US
dc.subjectSuccinic Aciden_US
dc.subjectB-MOFen_US
dc.titleStudy of structural, surface and hydrogen storage properties of boric acid mediated metal (sodium)-organic frameworksen_US
dc.typearticleen_US
dc.relation.journalJournal of Molecular Structureen_US
dc.departmentHitit Üniversitesi, Fen Edebiyat Fakültesi, Kimya Bölümüen_US
dc.authorid0000-0003-4767-6799en_US
dc.identifier.volume1157en_US
dc.identifier.startpage159en_US
dc.identifier.endpage164en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US


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